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PA6 vs PA66 Explained: Key Differences and Which Is Better

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When you look at PA6 and PA66, you see they are used for different things. PA6, also known as nylon 6, is good for many basic uses. PA66, called nylon 6/6, is better when you need to handle heat or need extra strength. Both types are used in cars, electronics, and things people buy because they are strong and tough. They also do not cost too much. If you are not sure which one to pick, I can help you find the right choice for your project.

  • Automotive: Light and strong

  • Electrical: Keeps heat away, fights chemicals



  • PA6 is strong and bends easily. It does not cost much. This makes it good for things we use every day, like car parts and electrical boxes.

  • PA66 is even stronger and can handle more heat. It works better for tough jobs, like engine parts and big machines.

  • Think about what your project needs. Check if it needs to handle high heat or heavy weight. This helps you pick PA6 or PA66.

  • Both PA6 and PA66 do not get damaged by chemicals. PA66 stays steady in rough places. This makes it good for things that need to last a long time.

  • You should always talk to experts. They can help you pick the best nylon for your job, especially if it is special work.


What Is PA6?

Nylon 6 Overview

Nylon 6 is a very common engineering plastic. It is part of the nylon family, also called polyamide. You can find nylon 6 in lots of things you use every day. It is strong, flexible, and not too expensive. Nylon 6 is made from a chemical called caprolactam. The way it is made gives it a special structure. This makes it different from other types of nylon.

Here is a table that shows how nylon 6 and another nylon compare:

Nylon Type

Monomer Used

Polymerization Type

Hydrogen Bonding Characteristics

Properties Comparison

PA6

Caprolactam

Ring-opening polymerization

Strong hydrogen bonding

High toughness, excellent strength, cost-efficient

PA12

Laurolactam

Ring-opening polymerization

Fewer hydrogen bonds

Softer, more flexible, hydrophobic, better dimensional stability

Nylon 6 is special because it forms strong hydrogen bonds. These bonds help make it tough and strong. You can find nylon 6 in car parts, electrical cases, and things people buy. If you want something that is strong and not too pricey, nylon 6 is a good pick.


Key Features

Nylon 6 has many features that make it popular. You can see these features in its properties:

Property

Value Range

Tensile Strength

60 to 80 MPa

Elongation at break

100-300%

Young's Modulus

2 to 4 GPa

Melting Point

215-225°C

Glass Transition Temp

47-55°C

Density

~1.14 g/cm³

Dielectric Strength

Good insulator

  • Nylon 6 has a tensile strength from 60 to 80 MPa. This means it is strong enough for many jobs.

  • It can stretch 100% to 300% before breaking. Nylon 6 bends and stretches without snapping.

  • Its melting point is about 215-225°C. You can use it where there is some heat.

  • Nylon 6 is a good electrical insulator. This keeps it safe for electronics.

Tip: If you want something strong, flexible, and affordable, nylon 6 is a smart choice. You can use it in cars, electronics, and many other things.


Nylon 6 does not wear out fast and can take a hit. It has a smooth surface and can handle lots of use. Nylon 6 is better than pa66 when you need something to take a shock or be easy to make. That is why people like to use nylon 6 for tough parts.

Nylon 6 works well in many industries. You can count on it for lots of uses. At Suzhou UNIKING New Material Co., Ltd., we help you pick the best nylon for your needs.


What Is PA66?

Nylon 6/6 Overview

Some people call PA66 nylon 6/6. It is part of the nylon family, just like PA6. Nylon 6/6 is used in things that need to be strong and last long. It is made from two chemicals: hexamethylenediamine and adipic acid. These chemicals make a regular and tight structure. This makes nylon 6/6 different from nylon 6. The way the molecules are arranged gives nylon 6/6 more crystallinity and better thermal stability than PA6. Nylon 6/6 is used where heat and strength are very important.


Nylon 6/6 is special in the polyamide group. It is good for tough jobs. The way its molecules are lined up helps it resist wear and keep its shape under stress. You see nylon 6/6 in car parts, electrical connectors, and machines. If you need something that can take pressure and heat, nylon 6/6 is a great pick.


Key Features

Nylon 6/6 has many features that make it a favorite for hard jobs. Here are some important features:

  • High mechanical strength: Nylon 6/6 can hold heavy things and be used many times.

  • Excellent thermal stability: It melts at about 260°C, so it works in hot places.

  • Good impact resistance: Nylon 6/6 can take hits and does not break easily.

  • Outstanding chemical resistance: It stands up to oils, greases, and many chemicals.

  • Fatigue resistance: Nylon 6/6 stays strong even after lots of use.

Property

Value Range

Tensile Strength

75 to 95 MPa

Elongation at break

60-150%

Young's Modulus

2.5 to 3.5 GPa

Melting Point

~260°C

Glass Transition Temp

55°C (dry)

Density

~1.14 g/cm³

Dielectric Strength

Excellent

Note: Nylon 6/6 is best when you need something strong, heat-resistant, and tough. You find it in gears, bushings, and engine parts for cars.

Nylon 6/6 also works well in electrical and electronic things. It is a good insulator and fights off chemicals in harsh places. You can trust nylon 6/6 for parts that need to last and work well in hard conditions. At Suzhou UNIKING New Material Co., Ltd., I help you pick the right nylon 6/6 for your needs.


PA6 vs PA66: Structure

PA6 vs PA66


Chemical Differences

PA6 and PA66 are both types of nylon. They have different chemical structures. PA6 uses one building block called ε-caprolactam. PA66 uses two building blocks: 1,6-diaminohexane and adipic acid. These different building blocks change how the chains connect.

Polyamide

Monomer Composition

PA6

ε-caprolactam (CPL)

PA66

1,6-diaminohexane (HMDA) and adipic acid (AA)

Nylon 6 has a chain made from the same unit over and over. Nylon 6/6 uses two units, so its pattern is more regular. This regular pattern makes nylon 6/6 tighter and more ordered. Because of this, nylon 6 and nylon 6/6 act differently in real life.


Impact on Properties

The way each nylon is built changes how it works. PA6 has a chain that bends more easily. PA66 has a chain that is straighter and more regular. Nylon 6/6 forms crystals faster and has more crystals than nylon 6. This gives nylon 6/6 better shape and heat resistance. Nylon 6 is tougher and can take hits better.

Property

PA6

PA66

Molecular Chain

More flexible

More regular

Crystallization Rate

Slower

Faster

Crystallinity

50–60%

60–70%

Density

1.13 g/cm³

1.14 g/cm³

Impact

Better toughness and impact resistance

Better dimensional stability and heat resistance

If you want something that can bend and take a hit, pick nylon 6. If you need something strong that keeps its shape in heat, pick nylon 6/6. Both types work well, but your choice depends on what you need.

Tip: Think about what your project needs before you choose PA6 or PA66. At Suzhou UNIKING New Material Co., Ltd., I help you find the best nylon for your job.


PA6 vs PA66: Mechanical Properties

Strength & Stiffness

When you compare nylon 6 and nylon 6/6, you see differences in strength and stiffness. Nylon 6 gives you good strength for many applications. Nylon 6/6 offers even higher strength and stiffness, which makes it a top choice for demanding uses. You often see nylon 6 in parts that need to bend and flex. Nylon 6/6 works best in places where you need the part to hold its shape and resist heavy loads.

Here is a table that shows how pa6 vs pa66 compare in strength and stiffness:

Property

PA6

PA66

Tensile Strength

84 MPa

90 MPa

Tensile Strain at Yield

5%

4-5%

Tensile Strain at Break

35%

50%

Tensile Modulus of Elasticity

3,300 MPa

3,550 MPa

Nylon 6/6 has a higher tensile strength and modulus than nylon 6. This means nylon 6/6 can handle more force before breaking and stays stiffer under pressure. You should choose nylon 6/6 for gears, bushings, and other parts that need to stay strong over time. Nylon 6 is still a great option for many uses, especially when you want a balance between strength and flexibility.

Tip: If your project needs maximum stiffness and strength, nylon 6/6 is the better choice. Nylon 6 works well for parts that need to flex or absorb movement.


Impact Resistance

Impact resistance tells you how well a material can take a hit without breaking. Nylon 6 stands out for its toughness. You see nylon 6 used in parts that need to absorb shocks, like automotive clips or electrical housings. Nylon 6/6 also has good impact resistance, but it focuses more on strength and heat resistance.

  • PA6 spall strength: approximately 0.18 GPa

  • PA66 spall strength: approximately 0.23 GPa


Nylon 6/6 has a higher spall strength, so it resists cracking under sudden force. Nylon 6, however, absorbs impacts better and bends before breaking. You should pick nylon 6 for applications where parts get bumped or dropped often. Nylon 6/6 fits best in places where you need both impact resistance and high strength.


Nylon 6 and nylon 6/6 both belong to the polyamide family. Their mechanical performance makes them popular in many applications, from automotive to electronics. At Suzhou UNIKING New Material Co., Ltd., I help you choose the right nylon for your needs. You can trust our expertise to match your project with the best material.


PA6 vs PA66: Thermal Properties

Heat Resistance

You need to know how nylon handles heat before you choose it for your applications. Nylon 6 and nylon 6/6 show different levels of heat resistance. PA6 can work at higher continuous-use temperatures. You see PA6 used in places where heat builds up, like automotive engine covers or electrical housings. PA6 keeps its shape and strength up to 185°C. PA66 works well for short bursts at 149°C (300°F), but for long-term use, it stays stable up to 85°C (185°F). Nylon 6/6 is strong, but PA6 gives you better performance when you need to handle heat for a long time.

Here is a quick look at the continuous-use temperatures:

  • PA6: Continuous-use temperature up to 185°C

  • PA66: Short-term service temperature 149°C (300°F)

  • PA66: Long-term service temperature 85°C (185°F)

Tip: If your applications need to handle heat for long periods, nylon 6 is a smart choice. Nylon 6/6 works best for short-term heat exposure.


Melting Point

You must consider the melting point when you process nylon. PA6 and PA66 have different melting points, which affects how you mold or extrude them. PA6 melts at about 215-225°C. You can process PA6 at lower temperatures, which saves energy and makes manufacturing easier. PA66 starts melting at around 260°C. You need higher temperatures to mold PA66, and its processing window ranges from 260°C to 320°C. Nylon 6/6 gives you better dimensional stability at high temperatures, but nylon 6 is easier to shape.

Property

PA6

PA66

Melting Point

215-225°C

~260°C

Processing Temperature

220-250°C

260-320°C

Nylon can show different melting points based on its form, like powder, fiber, or film. This can change how you process it. You should always check the form of nylon before you start manufacturing. Nylon 6 and nylon 6/6 both belong to the polyamide family, but their melting points set them apart in many applications.

Note: When you work with Suzhou UNIKING New Material Co., Ltd., you get expert advice on choosing the right nylon for your needs. I help you match the thermal properties to your project for the best performance.


PA6 vs PA66: Chemical Resistance

Environmental Performance

You want your nylon parts to last in hard places. Both nylon 6 and nylon 6/6 can resist many chemicals. People use nylon 6 and pa66 where there are acids, bases, or cleaners. These polyamide materials do not get damaged by alkalis. Tests show the amide bond in nylon stays strong, even at pH 13. Nylon 6 and pa66 keep their shape and strength in most daily uses.


If you use nylon in very strong alkalis, it might change. The parts of nylon 6 and pa66 that are less crystallized can break down. This makes them weaker and less able to absorb energy. You should check the environment before picking nylon 6 or pa66. For most uses, both types are strong and last a long time.

Tip: Nylon 6 and pa66 are good for cars, electronics, and medical tools. They resist chemicals and make parts that last.


Oil & Solvent Resistance

You need nylon that can handle oils and solvents at work. Both nylon 6 and pa66 are great at resisting oils and many solvents. Nylon 6 is used in engine covers, gears, and connectors. Pa66 works well in bushings and electrical housings. These nylon types keep their properties when they touch oils, greases, and cleaning fluids.

Here is a table that shows oil and solvent resistance:

Material

Oil Resistance

Solvent Resistance

Stability in Corrosive Environments

PA6

Excellent

Excellent

Moderate

PA66

Excellent

Excellent

Superior

Nylon 6 and pa66 both resist oil and solvents, but pa66 is more stable in tough places. You should pick pa66 if your part faces strong chemicals or needs to last longer. Nylon 6 is still great for most uses, especially if you want it to bend and take hits.

Note: At Suzhou UNIKING New Material Co., Ltd., I help you pick the best nylon for your job. You get good advice and strong materials for your needs.


PA6 vs PA66: Processing

Molding & Extrusion

You might wonder how nylon 6 and pa66 are made into parts. Both need the right temperature and low moisture. You have to dry nylon before you use it. If you skip drying, your parts can get bubbles or weak spots. The table below shows the best settings for pa6 and pa66:

Parameter

PA6 Range

PA66 Range

Melt Temperature

240 - 270°C

270 - 300°C

Mold Temperature

55 - 80°C

55 - 80°C

Recommended Moisture Content

Maximum 0.2%

Maximum 0.2%

Thermal Stability Threshold

Up to 310°C

Up to 310°C

Optimal L/D Ratio

18:22

18:22

Pa66 needs a hotter melt temperature than pa6. This means you use more energy with pa66. Both types use about the same mold temperature. You must keep moisture very low for both. If you follow these tips, your nylon parts will be strong.

At Suzhou UNIKING New Material Co., Ltd., I use special machines and careful tests. This makes sure every batch is high quality. 


Ease of Manufacturing

You may want to know which nylon is easier to make into parts. Nylon 6 is easier to mold and shape because it melts at a lower heat. This means you can make parts faster and with fewer mistakes. Pa66 needs more heat and careful control. The table below shows how they do after six times through the process:

Property

PA6 (6th Cycle)

PA66 (6th Cycle)

Young's Modulus (MPa)

1595.76

66% reduction

Tensile Strength (%)

28% reduction

64% reduction

Elongation (%)

49% increase

52% increase

Nylon 6 keeps its strength better after being used many times. Pa66 can lose more strength if you do not control the process well. Pick nylon 6 if you want to make parts quickly and need them to take hits. Pa66 is better if you need parts that are strong and can handle heat.

Tip: Always check your machine settings and use good materials. At Suzhou UNIKING New Material Co., Ltd., I follow strict rules and use top standards like ISO and UL. You get nylon parts you can trust.

If you need help with pa6 or pa66, you can ask me for advice. I help you pick the best polyamide and make sure your parts work great.


PA6 vs PA66: Applications

Nylon 6 Uses

Nylon 6 Uses

Nylon 6 is used in many industries. It is strong and handles heat well. In cars, nylon 6 makes light parts like air intake manifolds and engine covers. These parts help cars weigh less and use less fuel. Nylon 6 is also in electrical connectors. These connectors must handle high heat in new cars.


Nylon 6 is important in making textiles. It is used in fibers for clothes, carpets, and strong fabrics. These products last long and can bend without breaking. In electronics, nylon 6 is used for cases, switches, and parts that hold circuit boards. It keeps important parts safe from heat and bumps.

Here is a quick list of main uses for nylon 6:

  • Automotive: 41% share, worth 2.0 USD Billion

  • Electrical & Electronics: 23% share, worth 1.1 USD Billion

  • Textiles: 18% share, worth 1.2 USD Billion

You can count on nylon 6 to work well in these jobs. At Suzhou UNIKING New Material Co., Ltd., I help you pick the right nylon 6 for what you need.

Tip: Nylon 6 is a good pick if you want something strong, flexible, and not too expensive.


Nylon 6/6 Uses

Nylon 6/6, called pa66, is used for tough jobs. You find pa66 in car fuel systems, engine parts, radiator tanks, and engine covers. These parts need to be strong and handle heat. In electronics, pa66 is used to keep electric parts safe. It is a great insulator and does not melt easily.


Pa66 is also used in planes, where parts must be strong and not change in heat. Factories use pa66 in machines that work in hard places. Sports gear like fishing lines, camping tools, and safety gear use pa66 because it lasts long.

Here is a table with common uses for pa66:

Sector

Applications

Automotive

Fuel systems, engine parts, radiator tanks, engine covers

Electrical

Insulating material for electronic components

Aerospace

Components needing high strength and thermal resistance

Industrial

Machinery components in tough environments

Sports & Recreation

Fishing lines, camping gear, protective sports gear

Pa66 is getting better with new types that resist heat and fire. Some new pa66 is made to be better for the planet. At Suzhou UNIKING New Material Co., Ltd., I help you choose the best pa66 for your needs.

Note: Pick nylon 6/6 when you need something that works well in hard or hot places.


PA6 vs PA66: Cost

Price Comparison

You might ask which material costs more. Most of the time, PA66 is pricier than PA6. This is because PA66 uses special chemicals that cost more. These are hexamethylenediamine and adipic acid. PA6 uses caprolactam, which is cheaper. PA66 also melts at a higher temperature. This means you need more energy to make it. That makes PA66 cost even more.

Here is a simple table to compare them:

Material

Typical Price (per kg)

Main Cost Drivers

PA6

Lower

Caprolactam, energy, demand

PA66

Higher

Adipic acid, diamine, energy

If you want to save money, PA6 is usually the best pick. PA66 is worth the extra money if you need it to be stronger or handle more heat.

Tip: Think about both the price and what you need the material to do. Sometimes, paying more for PA66 is smart if your parts last longer.


Market Factors

The price for PA6 and PA66 can change a lot. Many things in the world can make prices go up or down. Here are some things to watch:

  • The price of raw materials like caprolactam and adipic acid can change fast.

  • Supply and demand can shift quickly. Tariffs and how much is in stock matter too.

  • If cars need more nylon, prices can rise even if other industries slow down.

  • Problems with shipping or not enough supply can make prices jump.

  • Higher energy costs, especially in Europe, make it more expensive to make nylon.

The market for these plastics is always changing. If you work with Suzhou UNIKING New Material Co., Ltd., I help you watch these changes. My team uses good machines and tests to keep quality high and prices steady.

Note: When you plan your project, think about the price now and how it might change. This helps you make smart choices and stay on budget.


PA6 vs PA66: Pros & Cons

PA6 Advantages & Disadvantages

You might wonder why PA6 is a good pick or not. PA6 is strong, flexible, and not too expensive. Many industries use it, like cars and electronics. It is simple to shape and works well for making parts by injection molding. PA6 also stands up to rubbing and bending, so parts last longer and bounce back after bending.


Here is a table that lists the main good and bad points of PA6:

Advantages of PA6

Disadvantages of PA6

Excellent stiffness and abrasion resistance

Low melting point (220℃)

Suitable for injection molding

Hygroscopic, absorbs water from surroundings

Resistant to impact and wear

Loses strength and toughness when exposed to light and heat

High elasticity, returns to original shape

Not UV resistant, can discolor with UV exposure

Holds and shows dye well


PA6 is easy to recycle, which helps the planet. Studies show PA6 can be recycled many times and does not hurt the environment much. This makes PA6 a smart choice if you care about nature.

Tip: Pick PA6 if you want something tough, bendy, and easy to make. But remember, it can soak up water and get weaker in sunlight or heat.

PA6 can fail in some ways. Water can get inside and make it weaker. Heat and air can also break it down over time. Think about these things if you use PA6 outside or in hot places.


PA66 Advantages & Disadvantages

PA66 is stronger and works better in hard jobs. You see PA66 in cars, electronics, and machines that need to handle stress and heat. Adding glass fibers makes PA66 even tougher and stiffer. It keeps its shape and does not wear out fast, even after lots of use.

Here is a table that compares PA66 with glass fiber added:

Property

PA66 with 35% Glass Fibre

Impact Modified PA66 with 35% Glass Fibre

Tensile Strength

Best

Higher Strain

Flexural Strength

Best

Higher Toughness

Temperature Dependence

Yes

Yes

PA66 does well in bending, pulling, and hitting tests. Short glass fibers make PA66 blends even better. Even after recycling, PA66 with carbon fibers stays strong and keeps its shape. This means you can use it for strong parts and help the earth too.


PA66 has some downsides. It costs more than PA6 and needs more heat to make. It also takes in water, but not as much as PA6. Studies show PA66 is not as easy to recycle and has a bigger effect on the environment than PA6.

Material

Recyclability

Environmental Impact

PA6

High

Moderate

PA66

Moderate

High

Here are the main ways PA66 can fail:

  • Hydrolysis: Water can get in and make it weaker.

  • Thermo-oxidation: Hot air can break it down.

  • Thermal degradation: High heat can make it lose its good traits.

Note: Pick PA66 if you need something very strong, stiff, and good with heat. It is best for hard jobs, but it costs more and needs careful making.

If you are not sure which one to pick, I can help you. At Suzhou UNIKING New Material Co., Ltd., I give advice and offer top-quality plastics for your project.


Choosing Between PA6 and PA66

Decision Factors

You need to think about a few things before you pick PA6 or PA66. Each one is good for different jobs. You should match the material to what you need for strength, price, and how you will use it.

Here is a table to help you compare them:

Criteria

PA6

PA66

Mechanical Properties

Good toughness and impact resistance

Higher strength and better heat resistance

Processing Conditions

High processing flexibility

Requires more careful processing

Cost

Lower cost

Higher cost due to better properties

Application Suitability

Light load applications

High strength and heat resistance

Examples of Use

Machine instruments, wire insulation

Handles, high-temperature components

Ask yourself these questions:

  • Do you want more strength or more bend?

  • Will your part get hot?

  • Is saving money important?

  • Does your part need to fight off chemicals or water?

To help you choose, follow these steps:

  1. Check Temperature Needs: If your part gets hotter than 100°C for a long time, PA66 is usually best.

  2. Look at Loads: For heavy parts or stiff parts, PA66 or a stronger PA6/PA66 is good. If you want more bend, PA6 is better.

  3. Think About the Place: If your part is in a wet spot or near chemicals, pick a stable material.

  4. Think About Price: PA6 is a good deal for easy jobs.

  5. Check Sizes: For parts that must stay the same size, pick a material that does not change much after making.

Tip: Write down what you need for strength, heat, price, and where you will use it. This makes it easier to pick the right one.


Application Recommendations

You want your part to work well and last long. Picking the right material is important. Here are some tips for what to use:

Recommendation

Material

Performance Focus

High temperature deformation and structural rigidity

PA66-GF30

Extremely high requirements

Cost efficiency with slightly lower thermal performance

PA6-GF30

Cost control and efficiency

Rigidity, heat resistance, and mechanical strength

PA66

High performance applications

Cost control and processing efficiency

PA6

Budget-friendly options

If you need parts for cars, electronics, or machines that get hot or take hits, PA66 or PA66-GF30 is a strong pick. For lighter jobs or if you want to save money, PA6 or PA6-GF30 is a good choice.

You should talk to experts before you decide. At Suzhou UNIKING New Material Co., Ltd., I help you pick the best plastic for your job. You can ask for datasheets, guides, or even samples. I offer test runs and try-outs to make sure your parts work.

  • Talk to me or my team to check your choice.

  • Ask for datasheets and guides for each material.

  • Request samples or test pellets to try out.

  • Try making a sample part with 3D printing or a small mold.

Note: My experience and testing tools help you avoid mistakes and get great results. Many customers trust my advice and come back for more help.


If you have a hard job or need something special, contact me. I give custom advice and help from start to finish. You get good materials, quick help, and expert support all the way.

You have to pick the best material for your project. PA6 is tough and bends easily. PA66 is stronger and handles heat better.

  • PA66 is good for heavy or hot jobs.

  • PA6 is great when you want to save money and use it in many ways.

Application Area

PA6 Strengths

PA66 Strengths

Automotive

Bends, safe with chemicals

Hard, does not change shape easily

Electronics

Simple to make parts

Keeps its shape well

If you need help, you can ask me at Suzhou UNIKING New Material Co., Ltd. I help you pick the right polyamide for your project.


FAQ

What is the main difference between PA6 and PA66?

PA6 is better if you need something that can take a hit. It is also easier to make into parts. PA66 is stronger and can handle more heat. Pick the one that fits what you need for your project.


Can you use PA6 and PA66 for automotive parts?

Both PA6 and PA66 work in cars. PA6 is good for parts that need to bend. PA66 is best for engine covers and fuel systems because it is very strong.


Is PA6 or PA66 better for electrical applications?

Both give good insulation for electricity. PA66 is better if things get hot. Use PA66 for connectors and cases in places with high heat.


How do you decide which polyamide to use?

Write down what you need for strength, bending, price, and heat. I help you pick the best plastic for your job at Suzhou UNIKING New Material Co., Ltd.


Can you get custom nylon solutions?

Yes! I can make special nylon 6 and nylon 6/6 for you. You can ask for samples, help, and advice. Many people trust my materials because they work well.

PA6

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